3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 Material Safety Data Sheet Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 07/05/2005 Supercedes Date: Initial Issue Document Group: 20-1078-3 Product Use: Specific Use: Anaerobic Threadlocking Adhesive SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt POLYETHYLENE GLYCOL DIMETHACRYLATE 25852-47-5 60 70 TETRAETHYLENE GLYCOL DI-2-ETHYLHEXOATE 18268-70-7 20 -30 AMORPHOUS SILICA, TREATED 68909-20-6 5 -10 CUMENE HYDROPEROXIDE 80-15-9 1 -3 SACCHARIN 81-07-2 1 -2 CUMENE 98-82-8 0.05 -0.15 OPTICAL BRIGHTENER Trade Secret <= 0.1 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Thixotropic Liquid Odor, Color, Grade: Mild Odor, Blue Liquid General Physical Form: Liquid Immediate health, physical, and environmental hazards: Hazardous polymerization may occur. May cause severe eye irritation. May cause target organ effects. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Page 1 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Vapors released during curing may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Dust created by cutting, grinding, sanding, or machining may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. May be absorbed through skin and cause target organ effects. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Dust from cutting, grinding, sanding or machining may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. May be absorbed following inhalation and cause target organ effects. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May be absorbed following ingestion and cause target organ effects. Target Organ Effects: Prolonged or repeated exposure may cause: Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Contains a chemical or chemicals which can cause birth defects or other reproductive harm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES Page 2 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=212 †F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Water may be used to blanket the fire. Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: No unusual fire or explosion hazards are anticipated. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Collect as much of the spilled material as possible. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and MSDS. Collect the resulting residue containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. Page 3 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Avoid breathing of vapors, mists or spray. Avoid eye contact with vapors, mists, or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid contact with oxidizing agents. Keep container closed when not in use. Keep out of the reach of children. 7.2 STORAGE Store away from heat. Store out of direct sunlight. Store away from oxidizing agents. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide local exhaust ventilation at transfer points. Provide appropriate local exhaust for cutting, grinding, sanding or machining. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Full Face Shield, Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. Gloves made from the following material(s) are recommended: Butyl Rubber, Fluoroelastomer (Viton), Neoprene, Polyvinyl Alcohol (PVA). 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Fullface supplied-air respirator, Half facepiece or fullface air-purifying respirator with organic vapor cartridges, Half facepiece or fullface pressure demand self-contained breathing apparatus. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Do not ingest. Wash hands after handling and before eating. 8.3 EXPOSURE GUIDELINES Ingredient Authority Type Limit Additional Information CUMENE ACGIH TWA 50 ppm CUMENE OSHA TWA 50 ppm Skin Notation*; Table Z-1 CUMENE HYDROPEROXIDE AIHA TWA 1 ppm Skin Notation* Page 4 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 * Substance(s) refer to the potential contribution to the overall exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contact with the substance. Vehicles can alter skin absorption. SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Specific Physical Form: Thixotropic Liquid Odor, Color, Grade: Mild Odor, Blue Liquid General Physical Form: Liquid Autoignition temperature No Data Available Flash Point >=212 †F [Test Method: Tagliabue Closed Cup] Flammable Limits - LEL No Data Available Flammable Limits - UEL No Data Available Boiling point >=300 †F [@ 760 mmHg] Density 1.1 g/ml [@ 20 †C] Vapor Density 1.01 [Ref Std: AIR=1] Vapor Pressure <=5 mmHg Specific Gravity 1.1 [@ 20 †C] [Ref Std: WATER=1] pH No Data Available Melting point Not Applicable Solubility in Water Negligible Evaporation rate Negligible Viscosity 10,000 - 18,000 centipoise [@ 20 †C] [Test Method: Brookfield] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Strong oxidizing agents; Heat; Light Hazardous Polymerization: Hazardous polymerization may occur. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Storage Oxides of Nitrogen During Combustion Oxides of Phosphorus During Combustion Oxides of Sulfur During Combustion Toxic Vapor, Gas, Particulate During Combustion Page 5 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of completely cured (or polymerized) wastes in a sanitary landfill. Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, dispose of waste product in a facility permitted to accept chemical waste. EPA Hazardous Waste Number (RCRA): Not regulated Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 62-3494-0530-8, 62-3494-0535-7, 62-3494-1030-8, 62-3494-3930-7, 62-3494-5030-4 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Page 6 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM) Threadlocker 3494, Blue 07/05/2005 Ingredient CUMENE HYDROPEROXIDE C.A.S. No 80-15-9 % by Wt 1 -3 STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 1 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. No revision information is available. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 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