3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 Material Safety Data Sheet Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 09/13/2005 Supercedes Date: 12/14/2004 Document Group: 08-6485-0 Product Use: Specific Use: adhesive remover SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt CITRUS EXTRACT 8028-48-6 80 -90 PROPANE 74-98-6 10 -20 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Odor, Color, Grade: clear, pale yellow, sweet odor General Physical Form: Gas Immediate health, physical, and environmental hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Aerosol container contains flammable material under pressure. May cause allergic skin reaction. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Page 1 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 Skin Contact: Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Intentional concentration and inhalation may be harmful or fatal. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. 3.3 POTENTIAL ENVIRONMENTAL EFFECTS Chemical analysis of 3M Citrus Base Adhesive Remover yielded the following data: Chloride <10ppm, Fluoride <1ppm, Sulfur <4ppm, Total Halogen <10ppm. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of water. Get medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Page 2 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 Flash Point -50.00 †F Flammable Limits - LEL 2.1 % volume [Details: CONDITIONS: PROPANE] Flammable Limits - UEL 9.5 % volume [Details: CONDITIONS: PROPANE] 5.2 EXTINGUISHING MEDIA Use fire extinguishers with class B extinguishing agents (e.g., dry chemical, carbon dioxide). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Closed containers exposed to heat from fire may build pressure and explode. Extremely flammable liquid and vapor. Aerosol container contains flammable material under pressure. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Refer to other sections of this MSDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. Call 3M-HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Remove all ignition sources such as flames, smoking materials, and electrical spark sources. Use only non- sparking tools. Ventilate the area with fresh air. If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Close cylinder. If the cylinder can't be closed, place in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors. Dispose of collected material as soon as possible. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. Keep away from heat, sparks, open flame, pilot lights and other sources of ignition. Avoid eye contact with vapors, mists, or spray. Keep out of the reach of children. Vapors may ignite explosively. May cause flash fire. Prevent build-up of vapors - open all windows and doors. Maintain vapor concentrations below recommended exposure limits. Use only with cross-ventilation. Without adequate ventilation, vapors may settle in low-lying areas. Keep away from heat, sparks, and open flame. Do not smoke or ignite matches, lighters, etc. 7.2 STORAGE Store away from acids. Store away from heat. Store out of direct sunlight. Keep container in well-ventilated area. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Use with appropriate local exhaust ventilation. Provide appropriate local exhaust ventilation on open containers. Use with functioning spray booth or local exhaust. Do not use in a confined area or areas with little or no air movement. Use general dilution Page 3 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. Do not use in a confined area or areas with little or no air movement. If exhaust ventilation is not adequate, use appropriate respiratory protection. Provide ventilation adequate to control vapor concentrations below recommended exposure limits and/or control spray or mist. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection Avoid eye contact with vapors, mists, or spray. The following eye protection(s) are recommended: Safety Glasses with side shields. 8.2.2 Skin Protection Avoid skin contact. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. 8.2.3 Respiratory Protection Avoid breathing of vapors, mists or spray. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece air-purifying respirator with organic vapor cartridges. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water. 8.3 EXPOSURE GUIDELINES Ingredient PROPANE PROPANEAuthority ACGIH OSHAType TWA TWALimit 1000 ppm 1000 ppmAdditional Information Table Z-1 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Odor, Color, Grade: clear, pale yellow, sweet odor General Physical Form: Gas Autoignition temperature No Data Available Flash Point -50.00 †F Flammable Limits - LEL 2.1 % volume [Details: CONDITIONS: PROPANE] Flammable Limits - UEL 9.5 % volume [Details: CONDITIONS: PROPANE] Vapor Density Not Applicable Vapor Pressure 28 mmHg [@ 20 †C] [Details: Composite Vapor Pressure (Calculated)] Page 4 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 Specific Gravity 0.793 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Nil Evaporation rate No Data Available Volatile Organic Compounds Approximately 100 % [Test Method: calculated SCAQMD rule 443.1] Percent volatile Approximately 100 % weight VOC Less H2O & Exempt Solvents Approximately 100 % [Test Method: calculated SCAQMD rule 443.1] Viscosity Not Applicable SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Heat Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Condition Aldehydes During Combustion Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion Ketones Not Specified SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Page 5 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 Waste Disposal Method: Incinerate in a permitted hazardous waste incinerator. As a disposal alternative, dispose of waste product in a permitted hazardous waste facility. The facility should be equipped to handle gaseous waste. RECYCLE EMPTY AEROSOL CONTAINERS WHERE AVAILABLE. EPA Hazardous Waste Number (RCRA): D001 (Ignitable) Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 62-4667-2925-8, 62-4667-2928-2, 62-4667-2930-8, 62-4667-2935-7, 62-4667-4930-6, 62-4667-4932-2, 62-4667-4935-5 Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this material. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS), or are exempt polymers whose monomers are listed on EINECS. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. Page 6 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 4 Reactivity: 1 Special Hazards: None Aerosol Storage Code: 2 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Copyright was modified. Section 3: Immediate physical hazard(s) was modified. Section 3: Potential effects from skin contact information was modified. Section 3: Potential effects from inhalation information was modified. Section 3: Potential effects from ingestion information was modified. Section 5: Unusual fire and explosion hazard information was modified. Section 6: Release measures information was modified. Section 7: Handling information was modified. Section 7: Storage information was modified. Section 8: Engineering controls information was modified. Section 8: Eye/face protection phrase was modified. Section 13: Waste disposal method information was modified. Section 4: First aid for ingestion (swallowing) - decontamination - was modified. Section 4: First aid for ingestion (swallowing) - medical assistance - was modified. Section 15: 311/312 Delayed Hazard score was modified. Section 3: Immediate skin hazard(s) was added. Section 9: Vapor pressure value was added. Section 3: Other potential health effects heading was deleted. Section 3: Immediate other hazard(s) was deleted. Section 3: Other health effects information was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. Page 7 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Adhesive Remover 6040 / 6041 (Aerosol) 09/13/2005 3M MSDSs are available at www.3M.com Page 8 of 8