3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Material Safety Data Sheet Copyright, 2005, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes ADDRESS: 3M Center St. Paul, MN 55144-1000 EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours) Issue Date: 07/13/2005 Supercedes Date: 12/31/2002 Document Group: 11-2690-3 Product Use: Specific Use: curing hot melt adhesive SECTION 2: INGREDIENTS Ingredient C.A.S. No. % by Wt P,P'-DIPHENYLMETHANEDIISOCYANATE (MDI) 101-68-8 < 3 POLYURETHANE RESIN 31075-20-4 > 97 SECTION 3: HAZARDS IDENTIFICATION 3.1 EMERGENCY OVERVIEW Specific Physical Form: Waxy Solid Odor, Color, Grade: white/off-white, mild odor. General Physical Form: Solid Immediate health, physical, and environmental hazards: May cause allergic skin reaction. May cause thermal burns. May cause allergic respiratory reaction. 3.2 POTENTIAL HEALTH EFFECTS Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Page 1 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Thermal Burns: Signs/symptoms may include severe pain, redness and swelling, and tissue destruction. Skin Contact: Thermal Burns: Signs/symptoms may include intense pain, redness and swelling, and tissue destruction. Prolonged or repeated exposure may cause: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Moderate Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Inhalation: Vapors from heated material may cause irritation of the respiratory system. Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Prolonged or repeated exposure may cause: Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. Ingestion: Physical Blockage: Signs/symptoms may include cramping, abdominal pain, and constipation. Target Organ Effects: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. SECTION 4: FIRST AID MEASURES 4.1 FIRST AID PROCEDURES The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are followed. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Get immediate medical attention. Skin Contact: Remove contaminated clothing and shoes. Immediately flush skin with large amounts of cold water for at least 15 minutes. DO NOT ATTEMPT TO REMOVE MOLTEN MATERIAL. Cover affected area with a clean dressing. Get immediate medical attention. Wash contaminated clothing and clean shoes before reuse. Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention. If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never give anything by mouth to an unconscious person. Get medical attention. Page 2 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 SECTION 5: FIRE FIGHTING MEASURES 5.1 FLAMMABLE PROPERTIES Autoignition temperature No Data Available Flash Point >=390 † F Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable 5.2 EXTINGUISHING MEDIA Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam). 5.3 PROTECTION OF FIRE FIGHTERS Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA). Unusual Fire and Explosion Hazards: Not applicable. Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition information. SECTION 6: ACCIDENTAL RELEASE MEASURES Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be cleaned up by qualified personnel. Ventilate the area with fresh air. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. In the event of a release of this material, the user should determine if the release qualifies as reportable according to local, state, and federal regulations. SECTION 7: HANDLING AND STORAGE 7.1 HANDLING Avoid contact with water to prevent potentially violent reaction or fire. Avoid skin contact with hot material. Keep out of the reach of children. Keep container closed when not in use. Avoid breathing of dust created by cutting, sanding, grinding or machining. For industrial or professional use only. Avoid eye contact with dust or airborne particles. Do not expose to temperatures above 275 degrees F. 7.2 STORAGE Store away from heat. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 ENGINEERING CONTROLS Provide appropriate local exhaust for cutting, grinding, sanding or machining. Do not use in a confined area or areas with little or no air movement. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below Occupational Page 3 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Exposure Limits and/or control mist, vapor, or spray. If ventilation is not adequate, use respiratory protection equipment. 8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE) 8.2.1 Eye/Face Protection The following eye protection(s) are recommended: Safety Glasses with side shields, Indirect Vented Goggles. 8.2.2 Skin Protection Wear appropriate gloves, such as Nomex, when handling this material to prevent thermal burns. Avoid skin contact. Avoid skin contact with hot material. Select and use gloves and/or protective clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible materials. AIR SAMPLING DATA: The following 2 sets of air sampling data for p,p'-diphenylmethane diisocyanate (MDI) were collected from applications using a similar formulation. This data should be used as a guide in assessing isocyanate exposures. Each product user should monitor his/her own work environment and exposures. DATA SET 1: A). <0.0002 PPM (detection limit) @ 200F, B). 0.0003 ppm @ 225F, C.) 0.0004 ppm @ 250F, D.) 0.002 ppm @ 275F. The test condition for DATA SET 1 represents a continuous bead application from a Slautterbach MC-2, where the vapor collection was in the breathing zone of the applicator. DATA SET 2: A.) Operator breathing zone exposure to MDI vapor was found to be 0.0021 ppm during bench-top application with samples taken one foot above the surface of the material for 30 minutes. Material was heated to 250F with a Nordsen 506 unit and general room ventilation, flow rate was 126gr./min. B.) Operator breathing zone exposure to MDI vapor was found to be analytically undetectable (0.0008 ppm) during a pail changeover on the Nordson 506 unit with general room ventilation, changeover took approximately 20 min. 8.2.3 Respiratory Protection Avoid breathing of vapors. Avoid breathing of dust created by cutting, sanding, grinding or machining. Select one of the following NIOSH approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or fullface supplied-air respirator. Consult the current 3M Respiratory Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance. 8.2.4 Prevention of Swallowing Do not ingest. 8.3 EXPOSURE GUIDELINES Ingredient FREE ISOCYANATES FREE ISOCYANATES P,P'DIPHENYLMETHANEDIISOCYANATE (MDI) P,P'DIPHENYLMETHANEDIISOCYANATE (MDI) Authority 3M 3M ACGIH OSHAType TWA STEL TWA CEILLimit 0.005 ppm 0.02 ppm 0.005 ppm 0.02 ppmAdditional Information Table Z-1 SOURCE OF EXPOSURE LIMIT DATA: ACGIH: American Conference of Governmental Industrial Hygienists CMRG: Chemical Manufacturer Recommended Guideline OSHA: Occupational Safety and Health Administration AIHA: American Industrial Hygiene Association Workplace Environmental Exposure Level (WEEL) SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Page 4 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Specific Physical Form: Waxy Solid Odor, Color, Grade: white/off-white, mild odor. General Physical Form: Solid Autoignition temperature No Data Available Flash Point >=390 †F Flammable Limits - LEL Not Applicable Flammable Limits - UEL Not Applicable Boiling point 302 †F [Details: @ 5mm Hg (MDI)] Density 1.16 g/l Vapor Density 8.6 [Ref Std: AIR=1] [Details: MDI] Specific Gravity 1.16 [Ref Std: WATER=1] pH Not Applicable Melting point No Data Available Solubility in Water Nil Evaporation rate No Data Available Hazardous Air Pollutants 2 - 3 % weight [Test Method: Calculated] Volatile Organic Compounds <=1.0 g/l [Test Method: tested per EPA method 24] Percent volatile <=0.1 % weight VOC Less H2O & Exempt Solvents <=1.0 g/l [Test Method: tested per EPA method 24] Viscosity 16000 centipoise [Details: @ 250F (Brookfield) ] SECTION 10: STABILITY AND REACTIVITY Stability: Stable. Materials and Conditions to Avoid: Amines; Alcohols; Reaction with water, alcohols, and amines is not hazardous if container can vent to the atmosphere to prevent pressure buildup. Hazardous Polymerization: Hazardous polymerization will not occur. Hazardous Decomposition or By-Products Substance Amine Compounds Isocyanates Carbon monoxide Carbon dioxide Hydrogen CyanideCondition During Combustion During Combustion During Combustion During Combustion During Combustion Hazardous Decomposition: Do not expose to temperatures above 275 F. SECTION 11: TOXICOLOGICAL INFORMATION Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its components. Page 5 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 SECTION 12: ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION Not determined. CHEMICAL FATE INFORMATION Not determined. SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Method: Dispose of waste product in a sanitary landfill. Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal alternative, incinerate in an industrial or commercial facility. Empty containers are not hazardous waste as per U.S. EPA criteria. Empty 10 fl. oz. aluminum cartridges are recyclable using normal recycling techniques (See Decomposition Section). Since regulations vary, consult applicable regulations or authorities before disposal. SECTION 14:TRANSPORT INFORMATION ID Number(s): 62-3876-0430-9, 62-3876-4235-8, 62-3876-5230-8, 62-3876-5232-4, 62-3876-5235-7, 62-3876-7530-9, 62-3876-8530-8, 623876- 8550-6, 62-3876-8730-4, 62-3876-9530-7 Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M's transportation classifications are based on product formulation, packaging, 3M policies and 3M's understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: REGULATORY INFORMATION US FEDERAL REGULATIONS Contact 3M for more information. 311/312 Hazard Categories: Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - Yes Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Page 6 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Ingredient C.A.S. No % by Wt P,P'-DIPHENYLMETHANEDIISOCYANATE 101-68-8 < 3 (MDI) (Diisocyanates (EPCRA 313) ) STATE REGULATIONS Contact 3M for more information. CHEMICAL INVENTORIES The components of this product are in compliance with the chemical notification requirements of TSCA. Contact 3M for more information. INTERNATIONAL REGULATIONS Contact 3M for more information. WHMIS: Hazardous This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: OTHER INFORMATION NFPA Hazard Classification Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Revision Changes: Section 1: Product name was modified. Section 16: NFPA hazard classification heading was modified. Section 3: Other potential health effects heading was modified. Section 1: Division name was modified. Copyright was modified. Section 8: Exposure guidelines data source legend was modified. Section 3: Potential effects from skin contact information was modified. Section 5: Fire fighting procedures information was modified. Section 6: Release measures information was modified. Page 7 of 8 3M MATERIAL SAFETY DATA SHEET 3M(TM) Scotch-Weld(TM)Polyurethane Reactive Adhesive TE-030 07/13/2005 Section 7: Handling information was modified. Section 8: Engineering controls information was modified. Section 8: Skin protection phrase was modified. Section 13: Waste disposal method information was modified. Section 15: 311/312 hazard categories heading was modified. Section 15: International regulations information was modified. Section 15: State regulations information was modified. Section 15: US federal regulations information was modified. Section 15: WHMIS regulations information was modified. Section 10: Hazardous polymerization heading was modified. Section 14: Transportation legal text was modified. Section 3: Other health effects information was modified. Section 16: NFPA explanation was modified. Page Heading: Product name was modified. Section 15: Inventories information was modified. Section 15: EPCRA 313 text was modified. Section 12: Ecotoxicological information heading was modified. Section 12: Chemical fate information heading was modified. Section 16: NFPA hazard classification for special hazards was modified. Section 10: Hazardous decompostion heading was modified. Section 12: Ecotoxicological phrase was modified. Section 12: Chemical Fate phrase was modified. Section 8: Other skin protection comment was added. Section 11: Contact information toxicological data was added. Section 2: Ingredient phrase was added. Section 8: Eye/face protection phrase was deleted. Section 11: Product-based toxicology information comment was deleted. Section 11: Product-based toxicology information comment heading was deleted. DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M. 3M MSDSs are available at www.3M.com Page 8 of 8