|------------------------------------------------------- | | M A T E R I A L S A F E T Y D A T A S H E E T | |------------------------------------------------------- | |------------------------------------------------------------------------- | | SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION | |------------------------------------------------------------------------- | PRODUCT NAME : TITANIUM WINDOW & DOOR -CLEAR UPC NUMBER : 7079808671 (replacing DAP(R) DOW CORNING(R) TRADE MATE II(TM),MULTI-PURPOSE SIL SLT) PRODUCT USE/CLASS : Clear silicone caulk MARKETED BY: 24 HOUR EMERGENCY: DAP INC. TRANSPORTATION: 1-800-535-5053 (352-323-3500) 2400 BOSTON STREET MEDICAL : 1-800-327-3874 (513-558-5111) BALTIMORE, MD 21224 PREPARE DATE : 08/15/2000 GENERAL INFORMATION: REVISION NO. : 0 DAP INC. : 1-888-DAP-TIPS (1-888-327-8477) REVISION DATE: 08/15/2000 MANUFACTURED BY: Dow Corning Corporation 24 Hour Emergency Telephone: (517) 496-5900 South Saginaw Road Customer Service: (517) 496-6000 Midland, Michigan 48686 |------------------------------------------------------------------------- | | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |------------------------------------------------------------------------- | WT/WT % ITEM ------------ CHEMICAL NAME -------------CAS NUMBER RANGE 01 Polysiloxane TRADE SECRET 40.0-70.0 % 02 Isobutyl trimethoxysilane 18395-30-7 1.0-5.0 % 03 Methyltrimethoxysilane 1185-55-3 1.0-5.0 % 04 Metal alkoxide TRADE SECRET 1.0-5.0 % ---------------------- EXPOSURE LIMITS ------------------- - ACGIH OSHA COMPANY ITEM TLV-TWA TLV-STEL PEL-TWA PEL-CEILING TLV-TWA SKIN 01 N.E. N.E. N.E. N.E. N.E. 02 see methyl alcohol comments 03 see methyl alcohol comments 50 ppm 04 see n-butyl alcohol commentsNO NO NO (See Section 16 for abbreviation legend), * - TLV-Ceiling Value Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV-skin: TWA 200 ppm, STEL 250 ppm. n-Butyl alcohol is formed on contact with water or humid air. Provide adequate ventilation to control exposures within guidelines of OSHA PEL: TWA 100 ppm and ACGIH TLV-skin: ceiling 50 ppm. (Continued on Page 2) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS | |------------------------------------------------------------------------- | Remaining ingredients are not considered hazardous per the OSHA Hazard Communication Standard. Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); limits may vary between states. |------------------------------------------------------------------------- | | SECTION 3 - HAZARDS IDENTIFICATION | |------------------------------------------------------------------------- | EMERGENCY OVERVIEW: CAUTION! Prolonged or repeated contact with skin may cause irritation. May irritate eyes, skin, nose, and respiratory tract. POTENTIAL HEALTH EFFECTS: EFFECTS OF OVEREXPOSURE - EYE CONTACT: May cause eye irritation. EFFECTS OF OVEREXPOSURE - SKIN CONTACT: Prolonged or repeated contact with skin may cause irritation. EFFECTS OF OVEREXPOSURE - INHALATION: Vapor may cause nose and throat irritation. Vapor overexposure may cause drowsiness. EFFECTS OF OVEREXPOSURE - INGESTION: Low ingestion hazard in normal use. EFFECTS OF OVEREXPOSURE - CHRONIC HAZARDS: Repeated ingestion or swallowing large amounts may injure internally. MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED BY CONTACT: None known. PRIMARY ROUTE(S) OF ENTRY: SKIN CONTACT INHALATION |------------------------------------------------------------------------- | | SECTION 4 - FIRST AID MEASURES | |------------------------------------------------------------------------- | EYE CONTACT: Flush with large quantities of water until irritation subsides. Contact a physician. SKIN CONTACT: Wash with soap and water. INHALATION: Remove to fresh air. Contact a physician immediately. INGESTION: DO NOT INDUCE VOMITING. Contact a physician or Regional Poison Control Center immediately. COMMENTS: None. (Continued on Page 3) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 5 - FIRE FIGHTING MEASURES | |------------------------------------------------------------------------- | FLASH POINT: N.A. (SETAFLASH CLOSED CUP) LOWER EXPLOSIVE LIMIT: N.A. UPPER EXPLOSIVE LIMIT: N.A. AUTOIGNITION TEMPERATURE: N.E. EXTINGUISHING MEDIA: CO2 DRY CHEMICAL FOAM UNUSUAL FIRE AND EXPLOSION HAZARDS: None known. SPECIAL FIREFIGHTING PROCEDURES: As in any fire, wear self-contained breathing apparatus pressure-demand (MSHA/NIOSH approved or equivalent) and full protective gear. Use water spray to cool exposed surfaces. |------------------------------------------------------------------------- | | SECTION 6 - ACCIDENTAL RELEASE MEASURES | |------------------------------------------------------------------------- | SPILL OR LEAK PROCEDURES: Observe all personal protection equipment recommendations described in Sections 5 and 8. Wipe up or scrape up and contain for salvage or disposal. Clean area as appropriate since some silicone materials, even in small quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or detergents. Dispose of saturated absorbant or cleaning materials appropriately, since spontaneous heating may occur. Local, state, and federal laws and regulations may apply to releases and disposal of this material, as well as those materials and items employed in the cleanup of releases. You will need to determine which federal, state and local laws and regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding certain federal and state requirements. |------------------------------------------------------------------------- | | SECTION 7 - HANDLING AND STORAGE | |------------------------------------------------------------------------- | HANDLING INFORMATION: KEEP OUT OF REACH OF CHILDREN. Use with adequate ventilation. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide ventilation during use to control exposure within Section 8 guidelines or use air-supplied or self-contained breathing apparatus. Product evolves n-butyl alcohol when exposed to water or humid air. Provide ventilation during use to control n-butyl alcohol within exposure guidelines or use respiratory protection. Avoid eye contact. Avoid breathing vapor. Keep container closed. Do not take internally. STORAGE INFORMATION: Use reasonable care and store away from oxidizing materials. Keep container closed and store away from water or moisture. OTHER PRECAUTIONS: None. (Continued on Page 4) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 8 - EXPOSURE CONTROLS/PERSONAL PROTECTION | |------------------------------------------------------------------------- | ENGINEERING CONTROLS: Normal room ventilation. RESPIRATORY PROTECTION: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Not required under normal usage and adequate ventilation. EYE PROTECTION: Safety glasses with side shields recommended. SKIN PROTECTION: None required. OTHER PROTECTIVE EQUIPMENT: Product evolves flammable methyl alcohol when exposed to water or humid air. Provide ventilation during use to control exposure within Section 8 guidelines or use air-supplied or self-contained breathing apparatus. Product evolves n-butyl alcohol when exposed to water or humid air. Provide ventilation during use to control n-butyl alcohol within exposure guidelines or use respiratory protection. HYGIENIC PRACTICES: Although this product is not considered an eye irritant, inhalation hazard, or a skin contact hazard under normal conditions, it is advisable that personnel minimize skin contact, inhalation of vapors, and eye contact. Wash contaminated clothing before reuse. |------------------------------------------------------------------------- | | SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES | |------------------------------------------------------------------------- | BOILING RANGE : N.A. VAPOR DENSITY : N.A. ODOR : alcoholic odor APPEARANCE : translucent white EVAPORATION RATE: N.A. SOLUBILITY IN H2O : N.A. SPECIFIC GRAVITY : 1.03 VAPOR PRESSURE : N.A. PHYSICAL STATE : Paste (See Section 16 for abbreviation legend) |------------------------------------------------------------------------- | | SECTION 10 - STABILITY AND REACTIVITY | |------------------------------------------------------------------------- | CONDITIONS TO AVOID: None. INCOMPATIBILITY: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous vapors to form as described in Section 8. (Continued on Page 5) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 10 - STABILITY AND REACTIVITY | |------------------------------------------------------------------------- | HAZARDOUS DECOMPOSITION PRODUCTS: Thermal breakdown of this product during fire or very high heat conditions may evolve the following hazardous decomposition products: Silicon dioxide. Carbon oxides and traces of incompletely burned carbon compounds. Metal oxides. Nitrogen oxides. Formaldehyde. HAZARDOUS POLYMERIZATION: Will not occur under normal conditions. STABILITY: This product is stable under normal storage conditions. |------------------------------------------------------------------------- | | SECTION 11 - TOXICOLOGICAL PROPERTIES | |------------------------------------------------------------------------- | Complete information is not yet available. |------------------------------------------------------------------------- | | SECTION 12 - ECOLOGICAL INFORMATION | |------------------------------------------------------------------------- | No Information. |------------------------------------------------------------------------- | | SECTION 13 - DISPOSAL CONSIDERATIONS | |------------------------------------------------------------------------- | WASTE MANAGEMENT/DISPOSAL: Dispose of according to Federal, State, and Local Standards. This product does not meet the definition of a hazardous waste according to U.S. EPA Hazardous Waste Management Regulations, 40 CFR Section 261. State and Local regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the owner of the waste. EPA WASTE CODE - If discarded (40 CFR 261): None. |------------------------------------------------------------------------- | | SECTION 14 - TRANSPORTATION INFORMATION | |------------------------------------------------------------------------- | DOT PROPER SHIPPING NAME: Not Regulated by D.O.T. DOT HAZARD CLASS: NONE DOT UN/NA NUMBER: NONE PACKING GROUP: NONE (Continued on Page 6) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 15 - REGULATORY INFORMATION | |------------------------------------------------------------------------- | U.S. FEDERAL REGULATIONS: AS FOLLOWS - OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200) SARA SECTION 313: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: ----------- CHEMICAL NAME -----------CAS NUMBER WT/WT RANGE None. TOXIC SUBSTANCES CONTROL ACT: This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States: ----------- CHEMICAL NAME -----------CAS NUMBER No information available. NEW JERSEY RIGHT-TO-KNOW: The following materials are non-hazardous, but are among the top five components in this product: ----------- CHEMICAL NAME -----------CAS NUMBER Polysiloxane NJTSRN 14962700-5601P Polydimethylsiloxane 63148-62- 9 Amorphous fumed silica 112945-52- 5 Polysiloxane NJTSRN 14962700-5604P Metal alkoxide NJTSRN 14962700-5603P Methyltrimethoxysilane 1185-55- 3 Isobutyl trimethoxysilane 18395-30- 7 PENNSYLVANIA RIGHT-TO-KNOW: The following non-hazardous ingredients are present in the product at greater than 3% : ----------- CHEMICAL NAME -----------CAS NUMBER Polysiloxane Trade Secret Polydimethylsiloxane 63148-62- 9 Amorphous fumed silica 112945-52- 5 Polysiloxane Trade Secret CALIFORNIA PROPOSITION 65: WARNING: The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm: ----------- CHEMICAL NAME -----------CAS NUMBER None known (Continued on Page 7) Product Name: TITANIUM WINDOW & DOOR -CLEAR Revision Date: 08/15/2000 Page |------------------------------------------------------------------------- | | SECTION 15 - REGULATORY INFORMATION | |------------------------------------------------------------------------- | INTERNATIONAL REGULATIONS: AS FOLLOWS - CANADIAN WHMIS: This MSDS has been prepared in compliance with Controlled Product Regulations except for use of the 16 headings. CANADIAN WHMIS CLASS: No information available. |------------------------------------------------------------------------- | | SECTION 16 - OTHER INFORMATION | |------------------------------------------------------------------------- | HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 1 REACTIVITY: 0 PREVIOUS MSDS REVISION DATE: N.A. VOC less water, less exempt solvent: 45-50 g/ L VOC material : 45-50 g/ L LEGEND: ACGIH - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS N.A. - NOT APPLICABLE N.E. - NOT ESTABLISHED PEL - PERMISSIBLE EXPOSURE LIMIT NTP - NATIONAL TOXICOLOGY PROGRAM SARA - SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 STEL - SHORT TERM EXPOSURE LIMIT TLV - THRESHOLD LIMIT VALUE(8 HR. TIME WEIGHTED AVERAGE OR TWA) VOC - VOLATILE ORGANIC COMPOUND NJRTK - NEW JERSEY RIGHT TO KNOW LAW N.D. - NOT DETERMINED MSDS# 78671 (replacing MSDS# 8671) This data is offered in good faith as typical values and not as a product specification. No warranty either expressed or implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally applicable. However, each user should review the recommendations in specific context of the intended use and determine if they are appropriate. < End OF MSDS >