www.Titebond.comFranklin International MATERIAL SAFETY DATA SHEET MSDS Name: Titebond Multi-Purpose 100% Silicone White MSDS Number: 2601 Revision Date: 8/11/05 SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Titebond Multi-Purpose 100% Silicone White CAS Number: none HMIS Hazard Rating: Health: 1 Fire: 1 Reactivity: 0 Company Identification: Franklin International 2020 Bruck Street Columbus OH 43207 Contact: Franklin Technical Services Telephone/Fax: (800) 877-4583 (614) 445-1493 Emergency Phone (24 Hour): Franklin Security (614) 445-1300 Chemtrec (24 Hour): (800) 424-9300 Chemtrec International: (703) 527-3887 Product Class silicone elastomer Product Use: caulk sealant Product Code: Not applicable Division: Construction Adhesives & Sealants SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS Hazardous Ingredients CAS Number Percent methyltriacetoxysilane 4253-34-3 2.00 ethyltriacetoxsilane 17689-77-9 2.00 OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable. SECTION 3 - HAZARD IDENTIFICATION EMERGENCY OVERVIEW: CAUTION: IRRITANT. Direct contact with uncured caulk irritates eyes and skin. Overexposure to vapor may irritate eyes, nose and throat. Caulk may release acetic acid vapor (vinegar-like odor) during cure. Fully cured caulk is nonhazardous. KEEP OUT OF THE REACH OF CHILDREN. Material is a paste-like material that can be of various colors. ROUTES OF ENTRY: Inhalation: yes Ingestion: yes Skin: no Eye: yes INHALATION: May be irritating to upper respiratory tract. INGESTION: Ingestion is not a probable route of exposure. Single dose oral toxicity is considered to be extremely low. No hazard expected from swallowing small amounts incidental to normal handling operations. Ingestion may cause gastrointestinal irritation. SKIN: Prolonged or repeated skin contact may cause moderate irritation. EYE: Substance may cause moderate eye irritation. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: None identified. CARCINOGENICITY: IARC: No NTP: No OSHA: No REPRODUCTIVE TOXICITY: None currently known. TARGET ORGANS: Eyes, skin, and respiratory tract. SECTION 4 - FIRST AID MEASURES INHALATION: Remove to fresh air. If difficulty persists, seek medical attention. INGESTION: Call poison control center immediately. Follow their specific instructions. SKIN: Wash with soap and water or waterless cleaner. Contact a physician if irritation develops or persist. EYE: Hold eyelids apart and flush with plenty of water for at least 15 minutes. Seek medical attention. SECTION 5 - FIRE-FIGHTING MEASURES Flammability Class (OSHA) IIIB Flash Point: > 200.¯F Tag Closed Cup Explosive Range: Not applicable EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide, water spray, or ABC dry chemical when fighting fires involving this product. FIRE FIGHTING PROCEDURES: Wear a NIOSH approved self contained breathing apparatus. Wear appropriate personal protective equipment. Product will not burn but may spatter if temperature exceeds boiling point of water. After water evaporates, remaining material will burn. SECTION 6 - ACCIDENTAL RELEASE MEASURES CONTAINMENT TECHNIQUES: Use inert absorbent to dike the spill. Keep away from drains. CLEAN-UP: Spread absorbent over material and scrape up material/absorbent and place in an approved container. If product has dried scrape up and place in an approved container. SECTION 7 - HANDLING AND STORAGE HANDLING: Wash thoroughly after handling. Do not get material in eyes. Avoid breathing vapors. Avoid prolonged or repeated contact with the skin. STORAGE: Store in a cool, dry place. Avoid contact with moist air. PRECAUTIONARY STATEMENT: Keep out of the reach of children. SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION Occupational Exposure Limits ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL methyltriacetoxysilane N/est N/est N/est N/est N/est ethyltriacetoxsilane N/est N/est N/est N/est N/est Note: Product evolves acetic acid (CAS# 64-19-7) when exposed to moisture or humid air. The ACGIH TLV for acetic acid is 10.00 ppm with a 15-minute STEL of 15 ppm. The OSHA PEL for acetic acid is 10.00 ppm. ENGINEERING CONTROLS: Use appropriate ventilation as needed to maintain occupational exposure limits. OTHER: Facilities storing or utilizing any chemical should be equipped with an eyewash facility and a safety shower. RESPIRATORY PROTECTION: Respiratory protection is not expected to be necessary under normal use. Follow requirements for respiratory protection in OSHA 1910.134. EYE PROTECTION: Chemical splash goggles (ANSI Z87.1 or approved equivalent). SKIN PROTECTION: Where skin contact can occur, wear impervious gloves. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES Form: Paste Appearance/Color: White Odor: Acetic acid Solubility (in water): Nil pH Value: Not Available Boiling Range/Point: Not Available Evaporation Rate: Slower than n-Butyl Acetate % Volatile: < 5 Specific Gravity: 1.03 VOC: 32.0 g/l SECTION 10 - STABILITY AND REACTIVITY Stability: This product is stable Hazardous Polymerization: Hazardous polymerization will not occur CONDITIONS TO AVOID: None known. INCOMPATIBLITY: Water or damp air; product cures in the presence of moisture. Avoid oxidizing materials. HAZARDOUS DECOMPOSITION PRODUCTS: Acetic acid is released on hydrolysis. SECTION 11 - TOXICOLOGICAL INFORMATION Inhalation of Acetic Acid vapor is irritating to the eyes and respiratory system. Direct and prolonged contact with the skin is irritating. SECTION 12 - ECOLOGICAL INFORMATION This formulation has not been tested for environmental effects. SECTION 13 - DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Disposal of this product must comply with all applicable federal, state and local regulations. CONTAINER DISPOSAL: Disposal of this container should comply with all applicable federal, state and local regulations. SECTION 14 - TRANSPORT INFORMATION UN Number None UN Pack Group N/A UN Class Nonhaz ICAO/IATA Class Nonhazardous IMDG Class Nonhazardous Shipping Name Nonhazardous Packaging may not be approved for shipping by air. Please contact Franklin International for further information. SECTION 15 - REGULATORY INFORMATION TSCA (Toxic Substances Control Act Inventory): All components of this product are listed on the TSCA inventory except as exempted. PENNSYLVANIA: Nonhazardous components required to be listed at 3% or more: amorphous silica 7631-86-9; polydimethylsiloxane 63148-62-9 NEW JERSEY: fumed amorphous silica 7631-86-9; methyltriacetoxysilane 4153-34-3; ethyltriacetoxysilane 17689-77-9; polydimethylsiloxane 63148-62-9; dimethyl siloxane, hydroxy-terminated 70131-67-8 SECTION 16 - OTHER INFORMATION DISCLAIMER: While the information and recommendations set forth herein are believed to be accurate as of the data hereof, Franklin International makes no warranty, express or implied, with respect thereto and disclaims all liability from reliance thereon.